Ammonia-Based Flue Gas Desulfurization Technology for Industrial Boiler SO2 Removal

Product Details

Ammonia-Based Flue Gas Desulfurization Technology for Industrial Boiler SO2 Removal

Overview

Ammonia-based flue gas desulfurization technology uses liquid ammonia or aqueous ammonia to remove sulfur dioxide (SO₂) from flue gas. The process simultaneously produces high-quality ammonium sulfate ((NH₄)₂SO₄) as a valuable byproduct. This technology is particularly well-suited for large coal-fired power plants and chemical facilities burning inexpensive high-sulfur fuels. While using ammonia that may otherwise be waste, the process generates high-grade, high-purity ammonium sulfate. This approach is increasingly becoming the mainstream technology for cyclic economy comprehensive utilization in large-scale flue gas desulfurization projects.

Process Characteristics

  • Mature Technology: Demonstrated on flue gas volumes from 500 MW class units.
  • Scale Resistance: The absorber tower does not suffer from scale formation.
  • Wide Fuel Sulfur Adaptability: Suitable for high-sulfur coal, high-sulfur heavy oil, and high-sulfur petroleum coke. No secondary pollution.
  • Valuable Byproduct: Ammonium sulfate has wide application as fertilizer.
  • Low Ammonia Slip: NH₃ slip is less than or equal to 10 ppm.
  • High Removal Efficiency: Easily achieves high SO₂ removal efficiency, typically greater than 95 percent.
  • Simple System Design: Fewer process steps compared to some other technologies.
  • Compact Equipment: Smaller equipment footprint than some alternatives.
  • High Absorbent Utilization: Efficient use of ammonia reagent.
  • Waste-to-Value: Sale of the ammonium sulfate byproduct provides good economic returns.

Application Range

The ammonia-based FGD process is suitable for the following applications:

  • Medium to large new or retrofit units, typically 50 MW and larger
  • Coal gasification plants requiring sulfur removal from synthesis gas
  • Fuel sulfur content of 0.5 to 5 percent or higher
  • Petroleum refining process streams requiring sulfur removal
  • Required SO₂ removal efficiency of 95 percent or greater
  • Locations near fertilizer plants that produce synthetic ammonia (providing a stable ammonia supply and ammonium sulfate off-take)
  • Power plants in saline or alkali soil regions where ammonium sulfate fertilizer is particularly valuable

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